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The Blue Sky Conferences on Catalytic Olefin Polymerization are scientific forums organized periodically by the Laboratory of Stereoselective Polymerizations (LSP) of the Federico II University in Naples (Italy) in collaboration with the Dutch Polymer Institute (DPI). General aim of a Blue Sky Conference is to offer five enjoyable days of good science in the title field. To this end, world-leading experts are invited to introduce and discuss, interactively with the audience, frontier topics in Key-Note Lectures of approximately 45 min without the menace of a chairman’s bell, and to be then available for a free-running, highly interactive and possibly provocative discussion.