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The correlation between peak luminosity and rate of decline in luminosity for Type I supernovae was first studied by B. W. Rust [Ph.D. thesis, Univ. of Illinois (1974) ORNL-4953] and Yu. P. Pskovskii [Sov. Astron., 21 (1977) 675] in the 1970s. Their work was little-noted until Phillips rediscovered the correlation in 1993 [ApJ, 413 (1993) L105] and attempted to derive a calibration relation using a difference quotient approximation Δm15(B) to the decline rate after peak luminosity Mmax(B). Numerical differentiation of data containing measuring errors is a notoriously unstable calculation, but Δm15(B) remains the parameter of choice for most calibration methods developed since 1993. To succeed, it should be computed from good functional fits to the lightcurves, but most workers never exhibit their fits. In the few instances where they have, the fits are not very good. Some of the 9 supernovae in the Phillips study required extinction corrections in their estimates of the Mmax(B), and so were not appropriate for establishing a calibration relation. Although the relative uncertainties in his Δm15(B) estimates were comparable to those in his Mmax(B) estimates, he nevertheless used simple linear regression of the latter on the former, rather than major-axis regression (total least squares) which would have been more appropriate.Here we determine some new calibration relations using a sample of nearby "pure" supernovae suggested by M. V. Pruzhinskaya [Astron. Lett., 37 (2011) 663]. Their parent galaxies are all in the NED collection, with good distance estimates obtained by several different methods. We fit each lightcurve with an optimal regression spline obtained by B. J. Thijsse's spline2 [Comp. in Sci. & Eng., 10 (2008) 49]. The fits, which explain more that 99% of the variance in each case, are better than anything heretofore obtained by stretching "template" lightcurves or fitting combinations of standard lightcurves. We use the fits to compute estimates of Δm15(B) and some other calibration parameters suggested by Pskovskii [Sov. Astron., 28 (1984) 858] and compare their utility for cosmological testing.