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Whitlockited is a new ferroelectric family combining laser, optical non-linear and ferroelectric properties with Ca2+ ionic conductivity. Divalent cation conductivity is rare, and at present is still unknown to co-exist with ferroelectricity. The purpose of this work was to study dependence of Ca2+-conductivity on crystal structure peculiarities, optic amd dielectric properties of the Whitlockites
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