ИСТИНА

The ligand surrounding of metal ion plays exceptionally important role in the metal complex catalysis, direct ligand selection is one of the most effective methods of catalyst activity and selectivity control. The systems, containing the ligand, capable of participating in various stages of catalytic process are of special interest, as they are more active than classic metal complexes catalysts. This work aims at determination of rules of organic nitrogencontaining compounds’ promotion action in radical processes, catalyzed by metal complexes by the example of carbon tetrachloride addition to olefins and oxidative coupling of thiols.