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Thiophene-containing polymers, primarily polythiophene and its derivatives, have attracted the attention of researchers owing to their wide spectrum of properties, such as conductance, luminescence, and electroluminescence [1]. Earlier, we synthesized new arylene-bis(2-aminothiophene-3-carbonitrile)s (1) and (2) via the Gewald reaction [2, 3]. In our opinion, these compounds are promising as monomers for the synthesis of thiophene-containing polymers characterized by improved processibility and the ability to form polyconjugated structures. At the same time, the presence of nitrile groups in thiophene fragments is interesting from the standpoint of both the synthesis of polymers with new photoelectric properties and the feasibility of their subsequent chemical transformations.