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Effects Of Magnetic Field And Oxygen On Catalytic Hydroperoxide Decomposition In Mixed Micelles With Cationic Surfactantsдоклад на конференции
- Авторы: Kasaikina O.T., Potapova N.A., Pisarenko L.M.
- Международная Конференция : The X International Conference “Mechanisms of Catalytic Reactions” (MCR-X)
- Даты проведения конференции: 2-6 октября 2016
- Дата доклада: 4 октября 2016
- Тип доклада: Устный
- Докладчик: не указан
- Место проведения: Svetlogorsk, Kaliningrad region, Russia, Russia
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Аннотация доклада:
The retardation effect of oxygen and external magnetic field on the yield of radicals during hydroperoxide decomposition in catalytic nanoreactors was discovered. Mixed reverse micelles formed by the cationic surfactant (Surf) and hydroperoxide {mLOOH…nSurf} play the role of nanoreactors. Similar effects of oxygen and external magnetic field (60—150 mT) on the yield of radicals are observed in the catalytic radical decomposition of hydroperoxide in the presence of acetylcholine. It is noteworthy that the retardation effect of the magnetic field decreases in the presence of paramagnetic particles such as oxygen and relatively stable radical.
- Добавил в систему: Касаикина Ольга Тарасовна