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Nickel Supported on MOF-5 and UiO-66 in Vapor-Phase Hydrodechlorination of Chlorobenzeneдоклад на конференции
- Авторы: Agafonov A.A., Ivakin Yu D., Strokova N.E., Lokteva E.S.
- Международная Конференция : The X International Conference “Mechanisms of Catalytic Reactions” (MCR-X)
- Даты проведения конференции: 2-6 октября 2016
- Дата доклада: 3 октября 2016
- Тип доклада: Стендовый
- Докладчик: Agafonov A.A.
- Место проведения: Svetlogorsk, Kaliningrad region, Russia, Russia
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Аннотация доклада:
In this work UiO-66 and MOF-5 were synthesized and used as carriers for Ni catalysts. Ni was supported by impregnation method from ethanol solution of Ni(acac)2 . Such produced Ni(acac)2/UiO-66 and Ni(acac)2/MOF-5 were characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), AAS, scanning electron microscopy (SEM), low-temperature N2 adsorption-desorption. Catalysts precursors were reduced by H2 at 300ºC during 3 h to form Ni/MOF-5 or Ni/UiO-66 in the catalytic reactor immediately before the catalytic tests in chlorobenzene (CB) hydrodechlorination (HDC) in vapor-phase in continuous-flow fixed bed catalytic system.
- Добавил в систему: Локтева Екатерина Сергеевна