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In the present report, we discuss the features of the formation and structure of inhomogeneities of aqueous solutions of poly-N-isopropylacrylamide (PNIPAM) as one of the most applied and studied thermoresponsive polymers using spin probe CW EPR. The effect is based on the greater affinity of TEMPO radical to hydrophobic media of the polymer associates. It manifests itself by appearing of the more broadened and hence less intensive signal of TEMPO radicals while heating compared to their water solutions at low temperatures.
№ | Имя | Описание | Имя файла | Размер | Добавлен |
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1. | Краткий текст | тезисы доклада | Golubeva_mdmr.pdf | 454,8 КБ | 8 ноября 2021 [kate_zub] |