ИСТИНА

3,7-Diazabicyclo[3.3.1]nonane scaffold (aka “bispidine”) found its application in various fields of medicinal chemistry and catalysis (see a chapter on review1) including both metal-mediated processes, organocatalysis and supramolecular catalysis. In this report the review of the recent developments in bispidine catalytic chemistry is presented together with our own results on application of chiral bispidine-terpene conjugates to Michael addition, addition of diethylzinc to chalcones2 and Henry reaction3. References 1. Antipin, I.S., et al. Russ. Chem. Rev. 2021, 90, 895. 2. Suslov, E.V., et al. Molecules 2021, 26, 7539. 3. Mozhaitsev, E.S., et al. Russ. J. Org. Chem. 2020, 56, 1969. This work is financially supported by the Russian Science Foundation (grant 19-73-20090).