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The aim of the present work is the determination of the complete set of standard formation functions of EmimCl and BmimCl in the crystal, liquid, and gaseous state: ∆_f H_298.15^0, ∆_f S_298.15^0, ∆_f G_298.15^0. For this purpose, a comprehensive thermodynamic study of two ionic liquids EmimCl and BmimCl were carried out by experimental and calculation methods.