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This work describes the synthesis, properties and application of new aliphatic and aromatic derivatives of heteroacenes in various optoelectronic devices - . The characteristics of organic field-effect transistors based on them, obtained by both solution and vacuum methods, have been investigated. Fast and simple technique based on Doctor Blade and Langmuir-Schaefer methods for functionalization of the semiconducting surface of C8-BTBT-C8 allowing to fabricate large scale biorecognition layer based on the novel functional derivative of BTBT containing biotin fragment as a foundation for further biomodification . As a proof-of-concept, we demonstrate the specific response of the BTBT-based biorecognition layer in EGOFETs to a virus of influenza A (H7N1 strain). The influence of dynamic disorder on charge transfer inside annelated organic semiconductors is also discussed.
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