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The interaction of micelles generated in aqueous of ionic amphiphilic diblock copolymers with oppositely charged macromolecules was shown to result in the formation of water-soluble micellar interpolyelectrolyte complexes with a "core-shell-corona" ("onion"-like) structure which represent novel polymeric nano-architectures. Properties of such complexes were examined with respect to variations of ionic strength and pH of the surrounding medium.