ИСТИНА

Cagelike metallasilsesquioxanes is a growing class of metallacomplexes with attractive (supra)molecular architectures and different applications.1, 2 Noncovalent mechanisms (metallocene, stacking, C-H…π or crown ether interactions) are non-trivial but influential effects governing the self-assembly of of metallasilsesquioxane cages/coordination polymers. Lecture will present recent results of our group in molecular design of metallasilsesquioxanes and investigation of their functionality. References 1. M. M. Levitsky, Y. V. Zubavichus, A. A. Korlyukov, V. N. Khrustalev, E. S. Shubina, A. N. Bilyachenko, J. Clust. Sci. 2021, 30, 1283. 2. A. N. Bilyachenko, N. Reis Conceição, M.F.C. Guedes da Silva, K.T. Mahmudov, G.B. Shul’pin, A.J.L. Pombeiro, Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes in Synthesis and Applications in Chemistry and Materials World Scientific, 2024 3. A. N. Bilyachenko, E. I. Gutsul, V. N. Khrustalev, G. S. Astakhov, A. Y. Zueva, Y. V. Zubavichus, M. V. Kirillova, L. S. Shul’pina, N. S. Ikonnikov, P. V. Dorovatovskii, E. S. Shubina, A. M. Kirillov, G. B. Shul’pin, Inorg. Chem. 2022, 61, 14800