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A method of high performance dry, steam and dry-steam reforming of biofermentation products into syn-gas on membrane catalytic systems was proposed. The membrane catalytic systems consist of porous inorganic membrane supports, prepared by self propagating high temperature synthesis and modified by nanosized metallocomplex components, which are uniformly distributed inside membrane pores. The influence of the composition of the supported active components, temperature, and flow rate on the activity and selectivity of substrate transformations into syn-gas, as well as the dynamics of theirs conversion on the membrane catalytic systems were studied.