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H2O-UO2(NO3)2-TBP system are considered as parts of developed mathematical model of a main system H2O-HNO3-UO2(NO3)2-TBP-Diluent. The equilibrium in H2O-UO2(NO3)2-TBP system was calculated using three methods. The average values are equal to KU=300.9 with errors about 1% and b1=-0,256 with errors about 10%.