Аннотация:New data are obtained on specific metasomatic associations of oxide minerals bearing chalcophile elements from metasomatic rocks of the orogenic zone related to the “Mixed series” metamorphic complex situated in the Pelagonian massif, Republic of Macedonia. Based on phase relations, the order of mineral formation is as follows: zincochromite + zircon + Zn-bearing talc + barite - franklinite + hetaerolite - gahnite - roméite + almeidaite - Fe3+-analogue of zincohögbomite - ferricoronadite + presumed Mn-analogue of plumboferrite. In the course of the metasomatic process occurring under highly oxidizing conditions, successive supply of Zn, Al, Sb and Pb resulted in the formation of Zn-spinels (including gahnite forming pseudomorphs after franklinite and hetaerolite), Sb-bearing Fe-analogue of zincohögbomite (epitaxy on Zn-spinels), and ferricoronadite (late hydrothermal veinlets). Supply of As occurred in two stages.