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Intracavity laser spectroscopy of the HfCl molecule. A new electronic transition 2Π3/2-X2Δ3/2статья
Информация о цитировании статьи получена из
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 апреля 2016 г.
- Авторы: Moskvitina E.N., Kuzyakov Yu Ya
- Журнал: Moscow University Chemistry Bulletin
- Том: 69
- Номер: 6
- Год издания: 2014
- Издательство: Allerton Press Inc.
- Местоположение издательства: United States
- Первая страница: 274
- Последняя страница: 281
- DOI: 10.3103/S0027131414060042
- Аннотация: The electronic absorption spectrum of hafnium monochloride (HfCl) has been investigated in the visible region in order to find the bands of HfCl related to the electronic states that were obtained from ab initio calculations. Two new bands that resulted from the transition from the X2Δ3/2 ground state to a 2Π3/2 electronic state predicted by calculations were detected in the spectrum of HfCl using the intracavity laser technique. A rotational analysis of these bands was carried out and previously unknown rotational constants for the 2Π3/2 state were determined: B 0 = 0.104977(34) cm−1 and a e = 0.00052(1) cm−1.
- Добавил в систему: Лабутин Тимур Александрович