Mathematical modeling of the evaporation kinetics for volatile coordination compoundsстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:http://www.maik.ru/cgi-perl/search.pl?type=abstract&name=inrgchem&number=2&year=99&page=241
Abstract.
Simulations were used to study the kinetics of evaporation of volatile coordination compounds accompanied by the formation of nonvolatile oligomers. The model involves a set of differential equations for the mass-action law. The potential of the model is illustrated for sublimation of copper(II) pivalate and the mixed-ligand complex of lanthanum acetylacetonate with o-phenanthroline. The solution of the inverse and
direct problems gave the rate constants for all processes involved and variations in the molar percentage with time for all reactants.