Influence of the nature of organic components in dinuclear copper(II) pivalates on the composition of thermal decomposition productsстатья
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Аннотация:Tetrabridged dinuclear complexes ((2-NH(2))C(5)H(4)N)(2)Cu(2)(mu(2)-OOCCMe(3))(4) (2 center dot C(6)H(6)) and ((3-NH(2))C(5)H(4)N)(2)Cu(2) (mu(2)-OOCCMe(3))(4) (3) and the cocrystallization product ((4-NMe(2))C(5)H(4)N)(2)Cu(eta(2)-OOCCMe(3))(2)center dot 2((4-NMe(2))C(5)H(4)N)(2)Cu(2)(mu(2)-OOCCMe(3))(4) (4) were synthesized by the reaction of the polymer [Cu(OOCCMe(3))(2)](n) (1) with aminopyridine ligands (L) of different nature (Cu: L = 1:1) in C(6)H(6). The solid-state thermal decomposition of these compounds was studied by differential scanning calorimetry and thermogravimetry, and their electrochemical behavior was investigated by cyclic voltammetry. All newly synthesized complexes were studied by X-ray diffraction, the magnetic properties of the complexes were investigated, and ESR measurements were performed. (C) 2010 Elsevier Ltd. All rights reserved.