Competitive cryochemical reactions of transition metal atoms, clusters and nanosized particlesстатья
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 4 февраля 2014 г.
Аннотация:Specific features of cryochemical reactions of tran-Specific features of cryochemical reactions of tran-sitionmetalatoms,smallclusters,complexesandnanoparticlessitionmetalatoms,smallclusters,complexesandnanoparticlesare considered. New phenomena that arise in nano- andare considered. New phenomena that arise in nano- andsubnanoscale systems at low temperatures are analysed. It issubnanoscale systems at low temperatures are analysed. It isshown thatthe competition between self-assemblyprocesses of shownthat thecompetition between self-assembly processes of metal atoms and reactions of metal aggregates of different sizemetal atoms and reactions of metal aggregates of different sizewith organic and inorganic reagents determines the chemicalwith organic and inorganic reagents determines the chemicalnature and properties of the intermediate and final products.nature and properties of the intermediate and final products.Special attention is paid to the analysis of sizeeffects caused bySpecial attention is paid to the analysis of sizeeffects caused bythe dependence of the reactivity of metal clusters and nano-the dependence of the reactivity of metal clusters and nano-particles onthenumber ofconstituent atoms. Prospects fortheparticles onthenumber ofconstituent atoms. Prospects fortheuse of competitive cryochemical reactions are discussed. Theuse of competitive cryochemical reactions are discussed. Thebibliography includes 185 referencesbibliography includes 185 reference.