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Trimethylsilyl ethers of amphiphilic carbosilane dendrimers of the third–fifths generations. Specific features of hydrolysis at the water-air interfaceстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 6 декабря 2018 г.
- Авторы: Tereshchenko A.S., Getmanova E.V., Buzin A.I., Ignat’eva G.M., Tatarinova E.A., Bystrova A.V., Myakushev V.D., Muzafarov A.M.
- Журнал: Russian Chemical Bulletin
- Том: 56
- Номер: 11
- Год издания: 2007
- Издательство: Springer Nature
- Местоположение издательства: Switzerland
- Первая страница: 2200
- Последняя страница: 2208
- DOI: 10.1007/s11172-007-0345-0
- Аннотация: Carbosilane dendrimers from the third to fifth generation with hydroxy groups in the surface layer of the dendrimer were synthesized, as well as their analogs with latent hydroxy groups. The dendrimers differ by the density of the carbosilane core and hydrophilic shell. The amphiphilic nature of the synthesized compounds was manifested already for more hydrophobic trimethylsilyl derivatives of dendrimers. This allowed one to observe the hydrolysis of these objects during compression of their monolayers at the water surface in the Langmuir bath. The parameters of the molecular structure of the dendrimers exert a determining effect on the rate and completeness of the hydrolysis.
- Добавил в систему: Терещенко Алексей Сергеевич