Thermodynamic Evaluation of Electrochemical Stability of Me — Si Systems (Me = 4th Row Transition Metal)статьяИсследовательская статья
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Статья опубликована в журнале из перечня ВАК
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 26 июня 2019 г.
Аннотация:This paper aims to review the studies of electrochemical properties of Me - Si binary systems for scandium, titanium, molybdenum, manganese, iron, cobalt, nickel, copper and zinc from the point of view of chemical thermodynamics. The binary phase diagrams of Me - Si and Me - O systems were considered and thermodynamic properties of metals silicides and oxides at standard conditions were collected. The potential - pH diagrams of Me - Si - H2O systems at 25 degrees C, air pressure of 1 bar and activities of ions in solution equal to 1 mol l(-1)were plotted. The corrosion-electrochemical behavior of studying systems was discussed.