Adsorption parameters of n-hexanol on single-crystal faces of bismuth: A regression analysis of the differential capacitance data and comparing the capacitance and chronocoulometry measurementsстатья
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Аннотация:The adsorption parameters of n-hexanol on the (111), (01(1) over bar), and (001) faces of single-crystal Bi electrodes are calculated using a nonlinear regression analysis of nonequilibrium differential capacitance curves within the model of two parallel capacitors supplemented with the Frumkin isotherm. Possible reasons for the discrepancy between the adsorption parameters obtained from the capacitance and chronocoulometric measurements are discussed.