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Reduction and re-oxidation behavior of calcium iron phosphate, Ca9Fe(PO4)(7)статья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Lazoryak B.I., Belik A.A., Kotov R.N., Leonidov I.A., Mitberg E.B., Karelina V.V., Kellerman D.G., Stefanovich S.Y., Avetisov A.K.
- Журнал: Chemistry of Materials
- Том: 15
- Номер: 3
- Год издания: 2003
- Издательство: American Chemical Society
- Местоположение издательства: United States
- Первая страница: 625
- Последняя страница: 631
- DOI: 10.1021/cm0108511
- Аннотация: Reduction (in H-2) and re-oxidation (in air) behavior of Ca9Fe(PO4)(7) was studied by X-ray powder diffraction, Mossbauer spectroscopy, thermogravimetry, hydrogen absorption, electrical conductivity, and magnetic-susceptibility measurements. The beta-Ca-3(PO4)(2)-like framework of Ca9Fe(PO4)(7) was stable in 100% H-2 up to 820 K. In the temperature range from 680 to 820 K, reversible redox reactions occurred without changing the stoichiometry of oxygen and phosphorus atoms and destroying the structure. The reduction process in Ca9Fe(PO4)(7) included the change of the oxidation state of Fe atoms and incorporation of hydrogen atoms into the structure to form Ca9FeHx(PO4)(7) (0 < x less than or equal to 1). Above 820 K, treatment in 100% H-2 was accompanied by loss in mass, partial destruction of the structure, and appearance of FeP and Fe2P phases. Re-oxidation studies in air showed that samples partially lost phosphorus atoms during reduction above 820 K. Behavior of CaqFe(PO4)(7) under a reduction atmosphere depended on H-2 concentration and temperature. At low H-2 concentration, the sample destruction started from ca. 870 K and proceeded with maintaining the oxidation state of Fe, releasing H2O, and forming a beta-Ca-3(PO4)(2)-like phase and beta-Ca2P2O7. In this case, iron phosphides appeared above ca. 1200 K.
- Добавил в систему: Лазоряк Богдан Иосипович