Differential approach to the memory-function reaction kineticsстатья
Статья опубликована в высокорейтинговом журнале
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Дата последнего поиска статьи во внешних источниках: 18 марта 2016 г.
Аннотация:A new formulation of the encounter theory for liquid-phase many-particle reacting systems (MPRS) is developed. This new formulation is based upon the notion of the pair distribution function and results in a set of partial differential equations equivalent to the integro-differential equations of the conventional approach. The solution is greatly improved by considering pair-particle interactions. The new formulation is applicable to arbitrary MPRS and allows for a general numerical solution. Applied to the Lotka-Volterra reaction, this approach revealed damping and increasing oscillations on the concentration, which cannot be seen in the framework of phenomenological chemical kinetics. (C) 2000 Elsevier Science B.V. All rights reserved.