Role of crystallographic heterogeneity in the calculation of the specific adsorption of ions on a polycrystalline electrode with the use of a mixed electrolyte with a constant ionic-strengthстатья
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Дата последнего поиска статьи во внешних источниках: 12 октября 2013 г.
Аннотация:An analysis of the capacitance curves of a polycrystalline electrode under the conditions of the specific adsorption of ions has been carried out in the framework of the model of ″independent electrodes″ . It is shown that in solutions with a sufficiently high ionic strength the virial adsorption isotherm with a correction for the diffuse electrical double layer formally describes the laws of the specific adsorption of ions in a polycrystalline electrode, but with values for the adsorption parameters differing significantly from those of the faces.