|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ИНХС РАН |
||
Charge-transfer in process of adsorption at electrode-solution interface - remarks on paper experimental determination and interpretation of electrosorption valency gamma by Schultze,J. and Vetter,Kстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 27 мая 2015 г.
- Авторы: Frumkin A., Damaskin B., Petrii O.
- Журнал: Journal of Electroanalytical Chemistry
- Том: 53
- Номер: 1
- Год издания: 1974
- Издательство: Elsevier Sequoia
- Местоположение издательства: Switzerland
- Первая страница: 57
- Последняя страница: 65
- DOI: 10.1016/0022-0728(74)80003-3
- Аннотация: A critical analysis shows that the approach to the estimation of the charge transfer in the process of adsorption at the electrode/solution interface used by Vetter and Schultze in the general case is not justified without introduction of non-thermodynamic models. This approach can prove useful in the investigation of the electric double layer within the limits of applicability of Grahame's model. A number of cases can however be cited where the approach of Schultze and Vetter is inapplicable. The conclusions of Schultze and Vetter regarding the adsorption of hydrogen at platinum are apparently based on some misunderstanding. In this case the thermodynamic approach6, 23 should be used. It would be more correct to call the quantity γ "the formal coefficient of charge transfer", rather than "the electrosorption valency". © 1974.
- Добавил в систему: Дамаскин Борис Борисович