A new heterobimetallic palladium-[60]fullerene complex with bidentate bis-1,1 '-[P](2)-ferrocene ligandстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:A new heterobimetallic palladium-[60]fullerene complex with ferrocene bis-phosphine ligand was prepared using alternative paths: either via addition reaction of Pd-2(dba)(3). C6H6 (dba = dibenzylidenacetone) in the presence of 1,1 '-bis(diphenylphosphino)ferrocene (dppf) to C-60, or via electrochemical activation of C-60 to generate C-60(2-) anions, which then react with PdCl2 and dppf to yield the target complex. The obtained (eta(2)-C-60)Pd(dppf) complex was characterized by H-1- and P-31-{H-1}-NMR and electronic spectroscopy as well as electrochemically. (C) 2000 Elsevier Science S.A. All rights reserved.