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Electrical double layer structure at a model liquid cadmium electrode in aqueous surface-inactive electrolytesстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 27 мая 2015 г.
- Авторы: Emets V.V., Damaskin B.B., Bagotskaya I.A., Mishuk V.Y.
- Журнал: Russian Journal of Electrochemistry
- Том: 36
- Номер: 6
- Год издания: 2000
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 661
- Последняя страница: 667
- Аннотация: A new electrode, a liquid Cd-Ga alloy (0.3 at. % Cd), is developed and studied. Its double-layer characteristics markedly differ from those of a Ga electrode and are virtually identical to those of a Cd electrode. In the absence of a chemisorption interaction between metal and solvent, its metallic capacitance is close to that of Ga, In-Ga, and Tl-Ga electrodes and differs from that of a Hg electrode. Its hydrophilicity is close to that of an In-Ga electrode. The chemisorption drop of potential of the solvent obtained for the Cd-Ga electrode fits the dependence typical for Ga, In-Ga, and Tl-Ga electrodes and correlates with the work function for the metal. Mercury does not fit this dependence, which is due to a larger separation between solvent dipoles and the metal (Hg) ionic core.
- Добавил в систему: Дамаскин Борис Борисович