Thermal Decomposition of Some Complexes of Alkylaluminums and Aluminum Hydridesстатья
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 26 сентября 2016 г.
Аннотация:Thermal decomposition of trimethylaluminum and some of its adducts, such as trimethylaluminum-
diethyl ether, trimethylaluminum -triethylamine, and triethylamine alane was studied. The compounds studied all feature gas evolution slowed down after 30 - 50% degree of decomposition of the starting material, with subsequent acceleration of the process. It is found that the thermal decomposition is catalyzed by its solid products. Probable reaction mechanisms are discussed.