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Studies on Preparation and Hydrogen Storage Properties of Dual-Metal Ferrocenyl Coordination Polymer Microspheresстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 9 июня 2016 г.
- Авторы: Sun Ruoli, Wang Li, Haojie Yu, Chen Yongsheng, Khalid Hamad, Abbasi Nasir M., Akram Muhammad, Vatsadze Sergey Z., Lemenovskii Dmitri A.
- Журнал: Journal of Inorganic and Organometallic Polymers and Materials
- Том: 26
- Номер: 3
- Год издания: 2016
- Издательство: Springer Verlag
- Местоположение издательства: Germany
- Первая страница: 545
- Последняя страница: 554
- DOI: 10.1007/s10904-016-0361-3
- Аннотация: A series of dual-metal ferrocenyl coordination polymer microspheres (M1M2-CPMs, M1M2 = CoMn, CoCu, MnCu) were synthesized by the reaction of 1,1′-ferrocene dicarboxylic acid with mixed metal salts via solvothermal method. From SEM and TEM images, it was found that all the as-synthesized coordination polymers showed microspheres structures. The products were also characterized by X-ray photoelectron spectroscopy (XPS), fourier transform infrared (FT-IR), powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). The M1M2-CPMs showed good thermostability and remained stable up to 250 °C. These M1M2-CPMs exhibited hydrogen uptake capacity. More interestingly, through the comparison among three microspheres we found that the M1M2-CPMs with hollow structures showed better hydrogen uptake.
- Добавил в систему: Вацадзе Сергей Зурабович