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Palladium complex of octaphenyl-substituted pyrazinoporphyrazine: synthesis, photochemical and photophysical propertiesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Дата последнего поиска статьи во внешних источниках: 11 ноября 2019 г.
- Авторы: Косов А.Д., Дубинина Т.В., Волов А.Н.
- Сборник: IOP Conference Series: Materials Science and Engineering
- Том: 525
- Год издания: 2019
- Место издания: IOP Publishing LTD, Великобритания
- Первая страница: 012027
- DOI: 10.1088/1757-899x/525/1/012027
- Аннотация: Novel palladium (II) tetrapyrazinoporphyrazinate, bearing eight peripheral phenyl groups, was obtained via metallation of the corresponding porphyrazine ligand. Target complex was identified using mass spectrometry, Fourier transform infrared and UV-Vis spectroscopy. Luminescence properties of palladium complex were investigated. Phosphorescence maximum of target compound was observed in the near IR region (828 nm). Singlet oxygen quantum yield (φ Δ ) was measured using the 1,3-diphenylisobenzofuran (DPBF) as the singlet oxygen trap. Value of ϕ Δ (0.35) is in a good agreement with literature data for porphyrazine complexes.
- Добавил в систему: Дубинина Татьяна Валентиновна