Rhodium Complexes with Chiral Cyclopentadienyl Ligands for Catalytic Synthesis of Dihydroisoquinolones from Aryl Hydroxamic Acids and Alkenes

Авторы: Trifonova E.A., Perekalin D.S.
Журнал: ИНЭОС OPEN
Том: 2
Номер: 4
Год издания: 2019
Издательство: Федеральное государственное бюджетное учреждение науки Институт элементоорганических соединений им. А. Н. Несмеянова Российской академии наук
Местоположение издательства: Москва
Первая страница: 124
Последняя страница: 129
DOI: 10.32931/io1917r
Аннотация: During the last ten years, cyclopentadienyl rhodium complexes have been extensively used for the C–H activation of aromatic compounds with various directing groups. However, the application of chiral rhodium catalysts for such enantioselective transformations has long remained an underdeveloped area. In this short review, we highlight recent results that demonstrate high potential of this field. In particular, we provide a comparative analysis of the available chiral rhodium complexes and their performances in the catalytic enantioselective annulation of aryl hydroxamic acids with alkenes. The current limitations and objectives for further development are also discussed.
Добавил в систему: Перекалин Дмитрий Сергеевич

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