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The Explanation of Magnetic Metal Carbon Mesocomposites Synthesis Peculiarities by Means of Mesoscopics Notionsстатья
- Авторы: Kodolov V.I., Kodolova-Chukhontzeva V.V., Terebova N.S., Shabanova I.N.
- Журнал: Academic Journal of Polymer science
- Том: 3
- Номер: 2
- Год издания: 2019
- Первая страница: 0046
- Последняя страница: 0048
- DOI: 10.19080/AJOP.2019.03.555613
- Аннотация: Mechanism of mesoparticles modification reactions are considered with the application of such notions as charges quantization, phase coherence, interference and annihilation. On the base of theoretical Mesoscopics ideas the formation of covalent bonds because of the interference of negative charges quants in modification reactions is discussed. The hypothesis about possibility of annihilation at the interaction of positive and negative charges quants in redox processes is presented. The magnetic metal carbon mesoscopic composites synthesis (for example, initial metal carbon Mesocomposites) is realized by mechanochemical method at the grinding of metal oxides microscopic particles with polyvinyl alcohol macromolecules. Then in the result the Copper or Nickel Carbon mesocomposites which have the following atomic magnetic moments: for Copper – 1,3 μB, for Nickel – 1,8 μB are obtained. The investigations are carried out on the analysis examples of processes of Copper and Nickel Carbon mesoparticles modification by the compounds containing p, d elements. In the middle of its such substances as polyethylene polyamine, ammonium iodide, ammonium polyphosphate (APP), silica (SiO2), aluminum oxide, iron oxide, nickel oxide and copper oxide are used. It’s noted that the red ox processes are accompanied by the metal atomic magnetic moments growth, that is explained by the electron shift on high energetic levels because of the annihilation phenomenon. The hypothesis concerning to the passing of two phenomena (annihilation and interference) at redox processes is proposed.
- Добавил в систему: Теребова Надежда Семеновна