The Study of the Oxidation of N,N,N',N'-Tetramethyl-p-Phenylenediamine for the Clarification of the Differences in the Mechanisms of Biocatalytic and Chemical Polymerization of Anilineстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из перечня ВАК
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 19 августа 2020 г.
Аннотация:The oxidation of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) using ammonium peroxydisulfateand the high redox potential laccase from Trametes hirsuta is studied in order to clarify the significant differences in the chemical and enzymatic polymerization reactions of aniline. As opposed to the laccase-catalyzed reaction, the chemical oxidation of TMPD proceeds in two stages. The radical cation formed at the first stage is oxidized by the peroxydisulfate ion to quinoiddiimine that can interact with the initial TMPD.The kinetics of the formation of the radical cation is studied by ultraviolet–visible (UV–Vis) andelectron paramagnetic resonance spectroscopy. The obtained data allow making an assumption about the difference in the mechanisms of chemical and enzymatic polymerization of aniline.