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Copper complexes with 1,10-phenanthrolines as efficient catalysts for oxidation of alkanes by hydrogen peroxideстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 28 октября 2020 г.
- Авторы: Shul'pina Lidia S., Vinogradov Mikhail M., Kozlov Yuriy N., Nelyubina Yulia V., Ikonnikov Nikolay S., Shul'pin Georgiy B.
- Журнал: Inorganica Chimica Acta
- Год издания: 2020
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Номер статьи: 119889
- DOI: 10.1016/j.ica.2020.119889
- Аннотация: The copper complexes with 1,10-phenanthrolines and 1,10- phenanthrolines-5,6-diones were synthesized and characterized by elemental analysis and spectra . One complex was characterized by X-ray analysis. The complexes turned out to be active in oxidations of cyclic, branched and linear alkanes. Hydrogen peroxide (50%) was used as an oxidant. The reactions were carried out in solvent acetonitrile at relatively the low temperatures (40-60 °C). Alkyl hydroperoxides are the primary products which partly decompose in the course of the reaction to produce mainly ketones (aldehydes) and alcohols. Treating the reaction mixture with PPh3 leads to the transformation of alkyl hydroperoxides (ROOH) to corresponding alcohols (ROH).
- Добавил в систему: Астахов Григорий Сергеевич
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