Neutron spectroscopy study of single-walled carbon nanotubes hydrogenated under high pressureстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:Single-walled carbon nanotubes (SWNT) were loaded with 5.2 wt% hydrogen at a hydrogen pressure of 3 GPa and T=620 K, quenched to 80 K and studied at ambient pressure and 15 K by inelastic neutron scattering (INS) in the range of energy transfers 3-400 meV. An analysis of the measured INS spectra showed that the quenched SWNT & H sample contained hydrogen in two different forms, as H atoms covalently bound to the carbon atoms (similar to 4.7 wt%) and as H-2 molecules (similar to 0.5 wt%) exhibiting nearly free rotational behavior. Annealing the sample in vacuum at 332 K removed about 65% of the H-2 molecules and annealing at 623 K removed all of them. This demonstrates that H-2 molecules were kept in this sample more tightly than in earlier studied SWNT & H samples that were hydrogenated at lower pressures and temperatures and lost all molecular hydrogen on heating in vacuum to room temperature.