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Macrocomplexes on the basis of functionalized polyethylene glycols and copolymers of ethylene oxide and propylene oxide: Synthesis and catalysisстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Дата последнего поиска статьи во внешних источниках: 12 октября 2013 г.
- Авторы: Karakhanov E.A., Kardasheva Yu S., Maksimov A.L., Predeina V.V., Runova E.A., Utukin A.M.
- Журнал: Journal of Molecular Catalysis
- Том: 107
- Номер: 1-3
- Год издания: 1996
- Первая страница: 235
- Последняя страница: 240
- Аннотация: Water soluble catalysts combining the properties of metal complexes and surfactants on the basis of terminally functionalized polyethylene glycols and block-copolymers of ethylene oxide and propylene oxide with various combinations of ethylene and propylene oxide fragments were investigated. Polymers, functionalized by dipyridyl and acetylacetone were used as ligands for preparation of Fe(III) and Co(II) complexes, which showed a high activity and selectivity in oxidation of cyclohexane and ethylbenzene by both hydrogen peroxide and oxygen. An aqueous phase hydroformylation rhodium catalyst was prepared on the basis of polyethylene glycols functionalized by phosphine groups.
- Добавил в систему: Максимов Антон Львович