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Redox processes in the Cu/(phen)/[B12H12]2−/solv system: Selective preparation of copper(I), copper(II), and heterovalent copper(I/II) compoundsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 24 февраля 2021 г.
- Авторы: Malinina Elena A., Kochneva Irina K., Polyakova Irina N., Avdeeva Varvara V., Goeva Lyudmila V., Minin Vadim V., Ugolkova Elena A., Kuznetsov Nikolai T.
- Журнал: Inorganica Chimica Acta
- Том: 477
- Год издания: 2018
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 284
- Последняя страница: 291
- DOI: 10.1016/j.ica.2018.03.024
- Аннотация: The complexation of copper and 1,10-phenanthroline (phen) in the presence of the [B12H12]2− anion is studied in organic solvents. The starting reagents contain copper(I) salts. The reactions are carried out in air and accompanied with oxidation of copper(I). Varying solvents and starting reagents, we succeeded in synthesizing selectively copper(I), copper(II), and heterovalent copper(I,II) complexes. Mononuclear, tetranuclear, and polymeric copper(II) complexes as well as a mononuclear copper(I) complex and a mixed cationic mononuclear copper(I)/copper(II) complexes are isolated and characterized by IR-spectroscopy and X-ray diffraction. The electronic structure of mononuclear copper(II) complex [CuII(phen)2Cl]2[B12H12] 2CH2I2 is studied by EPR.
- Добавил в систему: Уголкова Елена Александровна