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Application of Ni-based metal-organic framework as heterogeneous catalyst for disulfide addition to acetyleneстатья Исследовательская статья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 3 марта 2021 г.
- Авторы: Degtyareva Evgeniya S., Erokhin Kirill S., Ananikov Valentine P.
- Журнал: Catalysis Communications
- Том: 146
- Год издания: 2020
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Номер статьи: 106119
- DOI: 10.1016/j.catcom.2020.106119
- Аннотация: Several recent studies have shown unique adsorption activity of metal organic frameworks (MOFs) towards unsaturated hydrocarbons. In the current article, we explored the application of Ni-MOFs for S-functionalization of acetylene. We showed that Ni-MOF-74 catalyzed the reaction of disulfide addition to gaseous acetylene with excellent selectivity. The prime advantage of the proposed Ni-MOF-74 over other examined catalysts was its easy separation and recycling possibility. Moreover, it demonstrated no leaching of Ni species into the solution. The work was supplemented with a study on the catalyst behavior in the course of the reaction by using SEM, EDX, XRD, and FT-IR methods.
- Добавил в систему: Анаников Валентин Павлович