Coordination Properties of Hydroxyisophthalic Acids: Topological Correlations, Synthesis, Structural Analysis, and Properties of New Complexes

Sokolov, A.V.; Vologzhanina, A.V.; Barabanova, E.D.; Stefanovich, S.Y.; Dorovatovskii, P.V.; Taydakov, I.V.; Alexandrov, E.V.

Статья опубликована в высокорейтинговом журнале

Информация о цитировании статьи получена из Web of Science, Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 21 июня 2021 г.

Авторы: Sokolov Andrey V., Vologzhanina Anna V., Barabanova Ekaterina D., Stefanovich Sergey Yu, Dorovatovskii Pavel V., Taydakov Ilya V., Alexandrov Eugeny V.
Журнал: Chemistry - A European Journal
Год издания: 2021
Издательство: John Wiley & Sons Ltd.
Местоположение издательства: United Kingdom
Номер статьи: chem.202100733
DOI: 10.1002/chem.202100733
Аннотация: Hydroxyisophthalic acids are valuable polytopic ligands for the design of functional materials based on coordination polymers due to the variety of charges and coordination modes they possess. Here we describe synthesis, thermal stability, non‐linear optical and spectroscopic properties of five novel coordination compounds [K 2 L(H 2 O) 2 ], [MgL(H 2 O) 2 ]·3H 2 O, [CaL(H 2 O) 3 ], [SrL(H 2 O) 3 ]·H 2 O, [BaL(H 2 O)(H 2 O) 5 ] and one salt (NH 4 ) 2 L·2H 2 O with 4,5,6‐trihydroxyisophthalic acid ( H 2 L ), which has not been tested in the assembling crystalline coordination networks before. Peculiarities of the structural organization of the compounds were analyzed and compared with those for other hydroxyisophthalates. The coordination properties of hydroxyisophthalic acids were studied from the topological point of view. The comparative topological analysis of coordination and H‐bonded networks was performed. Structural correlations revealed in this study can be useful for the design of hydroxyisophthalate‐based coordination networks including porous metal‐organic frameworks, proton conductors, and NLO materials.
Добавил в систему: Вологжанина Анна Владимировна

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Coordination Properties of Hydroxyisophthalic Acids: Topological Correlations, Synthesis, Structural Analysis, and Properties of New Complexesстатья

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