Ruthenium Complexes Based on 5-MeC2B9-Carborane Ligand: Synthesis and Application in Polymerization Catalysis

Авторы: Zimina A.M., Anufriev S.A., Derendyaeva M.A., Knyazeva N.A., Somov N.V., Malysheva Yu B., Sivaev I.B., Grishin I.D.
Журнал: Doklady Chemistry
Том: 498
Год издания: 2021
Издательство: Pleiades Publishing, Ltd
Местоположение издательства: Road Town, United Kingdom
Первая страница: 30
Последняя страница: 37
DOI: 10.1134/S0012500821060057
Аннотация: Novel ruthenacarborane 3,3-(Ph2P(CH2)4PPh2)-3-H-3-Cl-9-Me-closo-3,1,2-RuC2B9H10 (1) and its derivatives 3,3-(Ph2P(CH2)4PPh2)-3-Cl-9-Me-closo-3,1,2-RuC2B9H10 (2), 3,3,8-(Ph2P(CH2)4PPh (3) and 3,3,4,8-(Ph2P(CH2)4P-(C6H4-о)2-3-Cl-9-Me-closo-3,1,2-RuC2B9H8 (4) were successfully obtained basing on a nido-carborane ligand bearing methyl substituent in lower bend of the cage [5-Me-7,8-C2B9H11]–. The obtained ruthenacarboranes keep the geometries and steric configurations typical for its unsubstituted analogues but are characterized by lower values of Ru(II)–Ru(III) redox potentials. It was shown that the obtained derivatives are active catalysts of controlled radical polymerization of MMA via ATRP mechanism.
Добавил в систему: Сиваев Игорь Борисович

	ИСТИНА	Войти в систему Регистрация
	ИСТИНА ИНХС РАН
	Главная Поиск Статистика О проекте Помощь

ИСТИНА