|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ИНХС РАН |
||
Восстановление рутения (IV) до рутения (III) в солянокислых водно-спиртовых растворах под действием микроволнового излучениястатья
Статья опубликована в журнале из списка RSCI Web of Science
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из перечня ВАК
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 23 августа 2019 г.
- Авторы: Башилов А.В., Федорова А.А., Рунов В.К.
- Журнал: Журнал аналитической химии
- Том: 55
- Номер: 12
- Год издания: 2000
- Издательство: ФГБУ "Издательство "Наука"
- Местоположение издательства: Москва
- Первая страница: 1250
- Последняя страница: 1255
- DOI: 10.1023/A:1026698516730
- Аннотация: The behavior of a kinetically inert form of ruthenium(IV), the μ-oxo-bis-[pentachlororuthenate(IV)] ion [Ru2OCl10]4–, was studied in aqueous alcohol solutions of hydrochloric acid under microwave radiation and upon the heating of the solutions. The conditions were selected for the quantitative reduction of ruthenium(IV) to ruthenium(III) with alcohols in 0.6–10 M HCl solutions in a microwave field. The maximum time it takes to reduce ruthenium(IV) under microwave radiation (30 min) was an order of magnitude shorter than that for heating the solutions in a boiling water bath. Regardless of the type of alcohol, the most rapid reduction of ruthenium(IV) was observed at the boundaries of the studied range of hydrochloric acid concentrations. It was found that, under microwave radiation, thermal effects were the driving force of the process in a 0.6 M HCl solution at 98°C, whereas, in 8–10 M HCl solutions, the contributions of nonthermal and thermal effects were comparable. It was shown that the reducing ability of saturated monoatomic C1–C4 alcohols increases with the number of carbon atoms and is also due to specific features of microwave radiation.
- Добавил в систему: Фёдорова Анна Александровна