Аннотация:Two ionization signals — selective and nonselective — are recorded on laser-induced evaporation of solid samples into a flame with subsequent exposure to resonance radiation. The magnitudes of the signals depend on many experimental parameters: the composition of the sample, the composition of the environment and gas mixture, etc. The dependences of the nonselective and selective signals on such experimental parameters as the voltage on the cathode and the energy of the vaporizing radiation have been studied. The optimum energy of the vaporizing radiation was 44–48 mJ at the cathode voltage 500–800 V. This has allowed the coefficient of correlation of the calibration graph to be raised up to 0.99. In these conditions, the limit of detection of Li was 0.017%.