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[Co(solv)6][B10H10] (solv = DMF and DMSO) for low-temperature synthesis of boridesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 февраля 2017 г.
- Авторы: Avdeeva V.V.a, Polyakova I.N.a, Vologzhanina A.V.b, Goeva L.V.a, Buzanov G.A.a, Generalova N.B.a, Malinina E.A.a, Zhizhin K.Y.a, Kuznetsov N.T.a
- Журнал: Russian Journal of Inorganic Chemistry
- Том: 61
- Номер: 9
- Год издания: 2016
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 1125
- Последняя страница: 1134
- DOI: 10.1134/S0036023616090023
- Аннотация: The synthesis and structure of complexes [Co(solv)6][B10H10] (solv = DMF and DMSO) have been reported. Both complexes have been prepared in a high yield by the reaction between cobalt(II) salts and closo-decaborates Cat2[B10H10] in the corresponding solvent. The complexes have been characterized by elemental analysis, IR and UV spectroscopy, X-ray powder diffraction, and X-ray crystallography. The thermal properties of the compounds have been studied in the temperature range 20–600°C under argon. The conditions to form cobalt borides have been determined based on the results of thermal analysis, subsequent annealing of the complexes in various conditions, and analysis of IR spectra of the resulting thermolysis products. © 2016, Pleiades Publishing, Ltd.
- Добавил в систему: Кузнецов Николай Тимофеевич