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Synthesis and structure of [NiL6][B10H10] (L = DMF or DMSO) as precursors for solid-phase synthesis of nickel(II) coordination compoundsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 февраля 2017 г.
- Авторы: Avdeeva V.V., Polyakova I.N., Goeva L.V., Buzanov G.A., Malinina E.A., Kuznetsov N.T.
- Журнал: Inorganica Chimica Acta
- Том: 451
- Год издания: 2016
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 129
- Последняя страница: 134
- DOI: 10.1016/j.ica.2016.07.016
- Аннотация: Synthesis and structure of complexes [NiL6][B10H10] (L = DMF (1) or DMSO (2)) are described. Both complexes have been prepared from nickel(II) chloride and (Et3NH)2[B10H10] in the corresponding solvent. Compounds 1 and 2 have been characterized by elemental analysis, IR spectroscopy, single-crystal and powder X-ray diffraction. Weak interactions between BH-groups of the boron cluster and CH-groups of DMF and DMSO molecules found in crystals 1 and 2 have been detected in the IR spectra. Complexes [NiL6][B10H10] (L = DMF, DMSO) can be applied in solid-phase synthesis of nickel(II) complexes with azaheterocyclic ligands. Complexes [NiL3][B10H10] (L = Bipy or Phen) have been selectively prepared by mechanical activation of 1 + 3Phen and 2 + 3Bipy mixtures. © 2016 Elsevier B.V.
- Добавил в систему: Кузнецов Николай Тимофеевич