IONIC HYDROGEN-BOND AND DEPROTONATION OF CATIONIC HYDRIDE [(ETA-5-C5ME5)2OSH]+A-статья
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Дата последнего поиска статьи во внешних источниках: 24 марта 2017 г.
Аннотация:Ionic hydrogen bond formation by protonated metallocene and the anion, [(eta5-C5Me5)2OsH]+...-OOCCF3, as the first stage of deprotonation was discovered by IR spectra in low polar solvents. The equilibrium between the molecular and ionic hydrogen-bonded complexes, (eta5-C5Me5)2OS...HOOCCF3, formed after proton transfer is investigated. The structure of the ion pairs [(eta5-C5Me5)2OsH]+A- (A = BF4, PF6, CF3SO3) in the solid state and solution are discussed.