NOVEL TYPES OF HYDROGEN-BONDS INVOLVING TRANSITION-METAL ATOMS AND PROTON-TRANSFER (XH...M, [MH]+...B, [MH]+...A-)статья
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Дата последнего поиска статьи во внешних источниках: 24 марта 2017 г.
Аннотация:The conditions governing the formation of hydrogen bonding involving transition metal atoms of the molecular, ion molecular and ionic types in low polar media were found. IR and UV-Vis spectral characteristics of these bonds were determined. Similarities between the spectral properties of hydrogen bonds with a metal atom and with common organic bases as well as some particular characteristics of the former were established. The equilibrium between molecular (OH...M) and ionic (O-...[HM]-) hydrogen-bonded complexes was investigated.