Intermolecular rearrangement of cobalt phenylsiloxanesстатья
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Аннотация:Intermolecular rearrangement of cobalt phenylsiloxanes was studied. The rearrangement leads to the formation Of Compounds with metal oxide moieties in the organosiloxane Structure and is accompanied by a change in the spectral characteristics of cobalt(II), determined by the second coordination sphere of the metal. The rate-determining step is the decomposition of an intermediate complex formed upon the coordination of the metal siloxane moieties.