Redox induced reactions of transition metal π- and σ,π-complexesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 24 марта 2017 г.
Аннотация:In this review, redox-induced reactions of pi- and sigma,pi-complexes leading to the selective formation (or cleavage) of C-H, C-C, and C-O bonds have been summarized. To illustrate the synthetic potential of such methodology, the following representative reactions studied in our group are discussed: (1) oxidatively induced hydrogen elimination from "open" cyclic diene and dienyl complexes resulting in formation of "closed" dienyl and arene complexes, respectively; (2) reductive activation of C-H bonds in diene, vinylidene, and carbyne complexes forming new multiple C-C bonds; (3) oxidative dehydrodimerization of vinylidene complexes into binuclear mu-divinylidene species; and (4) oxidatively induced addition of oxygen nucleophiles to mu-divinylidene complexes affording cyclic mu-dicarbene derivatives.